Heat capacity and phase equilibria of wadeite-type K2Si4O9     

Wenjun Yong  E. Dachs  A. C. Withers  E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

一种计算台风风场的方法     

陈孔沫 《热带海洋学报》1994,(2)

揭示Ｒａｎｋｉｎｅ涡风场模式和Ｊｅｌｅｓｎｉａｎｓｋｉ风场模式之间的联系，并设计了一种台风风场分布模式，它的风速分布曲线落在Ｊｅｌｅｓｎｉａｎｓｋｉ和Ｒａｎｋｉｎｅ涡两个风场模式的风速分布曲线之间，具有一个既优于Ｊｅｌｅｓｎｉａｎｓｋｉ又优于Ｒａｎｋｉｎｅ涡的风速衰减速率，因此它同时克服了Ｒａｎｋｉｎｅ涡模式计算风速偏小和Ｊｅｌｅｓｎｉａｎｓｋｉ模式计算风速偏大的缺点，以一种比较合理的变化趋势向远方衰减，成为一个比较切合实际的台风风场分布模式。同时，文中提出的移行台风风场计算方法对宫崎正卫、上野武夫和Ｊｅｌｅｓｎｉａｎｓｋｉ模式都有一定的改进。  相似文献   

On the structural evolution of the Central Trough in the Norwegian and Danish sectors of the North Sea     

Martin B. Gowers  Asbjrn Sbe 《Marine and Petroleum Geology》1985,2(4):298-318

The Central Trough of the North Sea is not a simple rift graben. It is an elongated area of regional subsidence which was initiated in mid Cretaceous times and continued to subside through to the late Tertiary. Its form is not representative of pre-mid Cretaceous tectonics.In Late Permian times the North Sea was divided into a northern and southern Zechstein basin by the E-W trending Mid North Sea-Ringkøbing-Fyn High. The latter was dissected by a narrow graben trending NNW through the Tail End Graben and the Søgne Basin. The Feda Graben was a minor basin on the northern flank of the Mid North Sea High at this time. This structural configuration persisted until end Middle Jurassic times when a new WNW trend separated the Tail End Graben from the Søgne Basin. Right lateral wrench movement on this new trend caused excessive subsudence in the Tail End and Feda Grabens while the Søgne Basin became inactive.Upper Jurassic subsidence trends continued during the Early Cretaceous causing the deposition of large thicknesses of sediments in local areas along the trend. From mid Cretaceous times the regional subsidence of the Central Trough was dominant but significant structural inversions occurred in those areas of maximum Early Cretaceous and Late Jurassic subsidence.  相似文献   

Numerical and simplified methods for the calculation of the total horizontal wave force on a perforated caisson with a top cover     

Xuefeng Chen  Yucheng Li  Bin Teng 《Coastal Engineering》2007

The VOF method and the k–ε model, combined with the equation of state of air at constant temperature, have been used to calculate the total horizontal wave force caused by monochromatic waves acting on a perforated caisson with a top cover. From comparison of various parameters, such as the total horizontal force, the pressure difference on the front wall, the pressure on the back wall and the pressure on the top cover, between the numerical results and test data, it can be seen that the numerical results agree well with the test data. It is concluded that the method described in this paper can be utilized to calculate wave forces acting on perforated caissons with a top cover in the case of nonovertopping, nonbreaking waves. A simplified method to calculate the total horizontal force has been developed, based on test data, using a least-squares method. A comparison between the numerical results and the values calculated from the simplified equations shows good agreement. Therefore the simplified equations can be used in engineering applications to evaluate the total horizontal force on a perforated caisson with a top cover.  相似文献   

黑潮区台风域海-气热输送量的计算          下载免费PDF全文

林晓能 《海洋与湖沼》1993,24(3):319-324

根据1972和1974年经过黑潮区的两个台风个例,计算和分析了台风各部位在不同的海气条件下热量输送的垂直分布特点。表明,在台风前部信风带中,热量垂直输送限于700hPa以下,在1000hPa处有约167.47—209.34J/(cm~2·h)的最大值,700hPa以上热量向下输送;在台风中心区,热量输送量最大,在1000hPa处接近420J/(cm~2·h),在850hPa附近可能有热输送量的最大值,其上随高度减小;在台风后部偏南气流中,向上热输送量较小;各层最大值不超过84J/(cm~2·h)。  相似文献   

长江口及济州岛邻近海域温、盐、密度的跃层现象     

孙日彦  周培强  赵继胜 《中国海洋大学学报(自然科学版)》1990,(1)

本文根据CTD观测资料,分析了研究海区的温、盐、密度跃层的分布与变化,讨论了逆温逆盐层的分布区域,并从跃层角度出发,分析了深层水的涌升,黄海冷水团的上边界以及台湾暖流在东海北部的影响范围。  相似文献   

斜坡提砌石护面厚度的计算     

张怀慧  李玉成 《海洋工程》2002,20(2):14-18

介绍了斜坡式防波堤砌石护面中的插砌条石和干砌块石在波浪作用下的力学图式及作用机理 ,重点给出考虑摩擦力作用时的砌石块体稳定厚度的计算公式 ,并结合工程实例验证了公式的适用性  相似文献   

港口靠船桩工作性状计算的双参数法   总被引：8，自引：0，他引：8  

谢耀峰 《海洋工程》2002,20(2):38-42,48

港口靠船桩是承受重复性荷载或多循环荷载的一种横向承载桩。双参数法能较好地描述靠船桩 (单桩、群桩 )的桩土工作性状。用双参数法进行计算时 ,所给的地面条件必须由重复荷载或多循环荷载作用下实测出来。根据现场试桩资料 ,标定桩土参数 ,即k =mx1/n的指数l/n、桩土相对柔度系数α、桩土综合刚度EI等值 ,可以用来设计试桩附近局部地区同类条件下的其它长桩。对于没有进行试桩的某些工程 ,可以联合运用双参数法和p -y曲线法进行桩的分析  相似文献   

Geoacoustic Inversion via Genetic Algorithm and Its Application to Manganese Sediment Identification     

Woojae Seong  Cheolsoo Park 《Marine Georesources & Geotechnology》2001,19(1):37-50

An acoustic inversion method using a wide-band signal and two near field receivers is proposed and applied to multiple layered seabed models including a manganese sediment. The inversion problem can be formulated into a probabilistic model comprised of signals, a forward model, and additive noise. The forward model simulates wide-band signals, such as chirp signals, and is chosen to be the source-waveletconvolution plane wave modeling method. The wavelet matching technique, using weighted least-squares fitting, estimates the sediment sound-speed and thickness on which determination of the possible numerical ranges for a priori uniform distribution is based. The genetic algorithm is applied to a global optimization problem to find a maximum a posteriori solution for determined a priori search space. Here the object function is defined by an L 2 norm of the difference between measured and modeled signals. Not only the marginal pdf but also its statistics are calculated by numerical evaluation of integrals using the samples selected during importance sampling process of the genetic algorithm.  相似文献   

Resources calculation of cobalt-rich crusts with the grid subdivision and integral method     

WU Ziyin  CHU Fengyou  MA Weilin  LI Shoujun  SHANG Jihong 《海洋学报(英文版)》2007,26(5):43-53

On the basis of three geological models and several orebody boundaries,a method of grid subdivision and integral has been proposed to calculate and evaluate the resources of cobalt-rich crusts on the seamounts in the central Pacific Ocean.The formulas of this method are deduced and the interface of program module is designed.The method is carried out in the software "Auto mapping system of submarine topography and geomorphology MBChart".This method and program will possibly become a potential tool to calculate the resources of seamounts and determine the target diggings for China's next Five-year Plan.  相似文献